未读消息消息

店铺

我的订单收藏

拍卖

拍卖交易我的竞拍收藏

我的好友资金账户

客服 |

帮助中心 9:00-20:30 在线留言

客服电话

010-89648155

服务时间

客服咨询 8:00-21:00

纠纷处理 9:00-21:00

图书审核 9:00-18:00

监督与建议

请选择

手机孔网

杂环化学(第3版)(英文版)

杂环化学(第3版)(英文版)

分享

作者: Thomas L.Gilchrist 著

出版社: 世界图书出版公司

出版时间: 1997-09

版次: 1

ISBN: 9787506233989

定价: 60.00

装帧: 平装

开本: 其他

纸张: 胶版纸

页数: 414页

分类: 自然科学

11人买过

The material of the second edition has been revised with two principal aims in mind. The first is to bring the contents up to date. To this end, Chapter 1 and several parts of other chapters have been rewritten, the references have been updated (with more emphasis given to recent review articles) and several new reaction schemes have been introduced. These new schemes are intended to illustrate aspects of heterocyclic chemistry that are becoming more important. Organopalladium and other organometaUic species are increasingly used in ring synthesis and in substitution reactions; some of the new schemes provide examples. New applications of heterocyclic compounds as pharmaceuticals, as intermediates in organic synthesis and as ligands are also illustrated. Preface to the third edition.

Preface to the second edition

Preface to the first edition

A cknowledgemen ts

1 Introduction: uses of heterocyclic compounds

2 Aromatic heterocycles

　2.1 The common structural types

　　2.1.1 Six-atom， six-π-electron heterocycles

　　2.1.2 Five-atom， six-π-electron heterocycles

　　2.1.3 Benzo-fused ring systems

　　2.1.4 Other fused heterocycles

　2.2 Some criteria of aromaticity in heterocycles

　　2.2.1 Bond lengths

　　2.2.2 Ring current effects and chemical shifts in 1H NMR spectra

　　2.2.3 Molecular orbitals and delocalization energy

　　2.2.4 Resonance energies

　　2.2.5 Dewar resonance energies and other calculated resonance energies

　　2.2.6 General conclusions

　2.3 Aromatic character and other types of unsaturated heterocycles

　　2.3.1 Monocyclic systems that conform to the Huckel rule

　　2.3.2 Other unsaturated heterocycles

  2.4 Reactivity of heteroaromatic compounds

  2.5 Tautomerism of heteroaromatic compounds

  Summary

  Problems

3 Nonaromatic heleroeydes

  3.1 Introduction

  3.2 Bond angle strain

    3.2.1 Angle strain and bonding in small-ring heterocycles

    3.2.2 Some consequences of bond angle strain in sr~lall rings

    3.2.3 Angle strain in larger rings

  3.3 Torsional energy barriers

    3.3.1  Single bonds

    3.3.2  Double bonds and partial double bonds

  3.4 Influence of bond lengths and van der Waals radii: conformadonal preferences of flexible heterocycles

    3.4.1 Saturated six-membered heterocycles

    3.4.2 Four- and flve-membered heterocycles

  3.5 Other types of interaction in saturated heterocycles

    3.5.1 'Through-bond' orbitaI interacflons: the anomeric effect

    3.5.2 Attractive 'through-space' interactions

  Summary

  Problems

4 Ring synthesis

  4.1 Introduction

  4.2  Cycllzation reactions

    4.2.1  Reaction types

    4.2.2 Displacement at saturated carbon

    4.2.3 Intramolecular nucleophilic addition to carbonyl groups

    4.2.4 Intramolecular addition of nucleophiles to other double bends

    4.2.5 Cyclization on to triple bonds

    4.2.6  Radical cyclization

    4.2.7 Carbene and nitrene cyclizatiml

    4.2.8 Electrocycllc reactions

  4.3 Cycloaddition reactions

    4.3.1 Reaction types

    4.3.2  1,3-Dipolar cycloaddition

    4.3.3 Hetero-Diels Alder reactions

    4.3.4  [2 + 2] Cyeloaddition

    4.3.5  Cheletropic reactions

    4.3.6 Ene reactions

  Summary

  Problems

5 Six-membered ring compounds with one heteroatom

6 Five-memeberd ring compounds with one heteroatom

7 Six-membered ring compounds with two or mor heteroatoms

8 Five-membered ring compoumnds with two or more heteroatoms

9 Three-and four-membered ring compounds

10 Seven-membered ring compoumds

11 Nomenclature

Answers and references to selected problems

Index
内容简介:
The material of the second edition has been revised with two principal aims in mind. The first is to bring the contents up to date. To this end, Chapter 1 and several parts of other chapters have been rewritten, the references have been updated (with more emphasis given to recent review articles) and several new reaction schemes have been introduced. These new schemes are intended to illustrate aspects of heterocyclic chemistry that are becoming more important. Organopalladium and other organometaUic species are increasingly used in ring synthesis and in substitution reactions; some of the new schemes provide examples. New applications of heterocyclic compounds as pharmaceuticals, as intermediates in organic synthesis and as ligands are also illustrated.
目录:
Preface to the third edition.

Preface to the second edition

Preface to the first edition

A cknowledgemen ts

1 Introduction: uses of heterocyclic compounds

2 Aromatic heterocycles

　2.1 The common structural types

　　2.1.1 Six-atom， six-π-electron heterocycles

　　2.1.2 Five-atom， six-π-electron heterocycles

　　2.1.3 Benzo-fused ring systems

　　2.1.4 Other fused heterocycles

　2.2 Some criteria of aromaticity in heterocycles

　　2.2.1 Bond lengths

　　2.2.2 Ring current effects and chemical shifts in 1H NMR spectra

　　2.2.3 Molecular orbitals and delocalization energy

　　2.2.4 Resonance energies

　　2.2.5 Dewar resonance energies and other calculated resonance energies

　　2.2.6 General conclusions

　2.3 Aromatic character and other types of unsaturated heterocycles

　　2.3.1 Monocyclic systems that conform to the Huckel rule

　　2.3.2 Other unsaturated heterocycles

  2.4 Reactivity of heteroaromatic compounds

  2.5 Tautomerism of heteroaromatic compounds

  Summary

  Problems

3 Nonaromatic heleroeydes

  3.1 Introduction

  3.2 Bond angle strain

    3.2.1 Angle strain and bonding in small-ring heterocycles

    3.2.2 Some consequences of bond angle strain in sr~lall rings

    3.2.3 Angle strain in larger rings

  3.3 Torsional energy barriers

    3.3.1  Single bonds

    3.3.2  Double bonds and partial double bonds

  3.4 Influence of bond lengths and van der Waals radii: conformadonal preferences of flexible heterocycles

    3.4.1 Saturated six-membered heterocycles

    3.4.2 Four- and flve-membered heterocycles

  3.5 Other types of interaction in saturated heterocycles

    3.5.1 'Through-bond' orbitaI interacflons: the anomeric effect

    3.5.2 Attractive 'through-space' interactions

  Summary

  Problems

4 Ring synthesis

  4.1 Introduction

  4.2  Cycllzation reactions

    4.2.1  Reaction types

    4.2.2 Displacement at saturated carbon

    4.2.3 Intramolecular nucleophilic addition to carbonyl groups

    4.2.4 Intramolecular addition of nucleophiles to other double bends

    4.2.5 Cyclization on to triple bonds

    4.2.6  Radical cyclization

    4.2.7 Carbene and nitrene cyclizatiml

    4.2.8 Electrocycllc reactions

  4.3 Cycloaddition reactions

    4.3.1 Reaction types

    4.3.2  1,3-Dipolar cycloaddition

    4.3.3 Hetero-Diels Alder reactions

    4.3.4  [2 + 2] Cyeloaddition

    4.3.5  Cheletropic reactions

    4.3.6 Ene reactions

  Summary

  Problems

5 Six-membered ring compounds with one heteroatom

6 Five-memeberd ring compounds with one heteroatom

7 Six-membered ring compounds with two or mor heteroatoms

8 Five-membered ring compoumnds with two or more heteroatoms

9 Three-and four-membered ring compounds

10 Seven-membered ring compoumds

11 Nomenclature

Answers and references to selected problems

Index

查看详情

相关分类

农业/林业畜牧/养殖生物科学环境科学数学物理学力学化学天文学测绘学地球科学大气科学（气象学）地质学海洋学

杂环化学(第3版)(英文版)含书签

九品

伊诺书店

北京市海淀区

平均发货20小时成功完成率94.53%

￥125.00

券

100减20

立即购买加入购物车
杂环化学(第3版)(英文版) 内页有少量划线

八五品

中豪书店

北京市昌平区

平均发货20小时成功完成率94.51%

￥88.00

券

100减20

立即购买加入购物车
杂环化学(第3版)(英文版)

九品

知音旧书店

江苏省常州市

平均发货21小时成功完成率94.48%

￥100.00

券

100减20

立即购买加入购物车
杂环化学（第3版）英文版正版内页干净实物拍摄

1997-09 印刷
印次: 1

九品

旧书藏宝阁

陕西省西安市

平均发货10小时成功完成率97.97%

￥116.00

券

100减20

立即购买加入购物车
杂环化学(第3版)(英文版)

八五品

湖南云顶书店

湖南省湘潭市

平均发货8小时成功完成率96%

￥88.00

券

100减20

立即购买加入购物车