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高等有机化学-结构与机理(第五版)

作者: [美] 卡雷（Carey.F.A.）著 , [美] 松德贝里（Sundberg.R.J.）著

出版社: 科学出版社

出版时间: 2009-01

版次: 1

ISBN: 9787030238573

定价: 160.00

装帧: 平装

开本: 16开

纸张: 胶版纸

页数: 1199页

字数: 1千字

正文语种: 英语

原版书名: Advanced Organic Chemistry

分类: 自然科学

1 张插图图片

　　《高等有机化学：结构与机理(第5版)》自从1997年面世以来，《高等有机化学》作为学科首选教材的地位一直没有动摇过，广泛地覆盖了有机化合物的结构、反应活性及合成。她的第五版相对2001年出版的第四版进行了大幅度的修订，更新了学科发展的相关资料，内容组织更加清晰明朗，特别是计算化学部分。PartA从化合物结构和立体化学基础概念讲起，涉及有机化学反应热力学和动力学的方方面面。主要反应类型涵盖亲核取代反应、加成反应、碳负离子和羰基化学反应、芳环取代反应、周环反应、自由基反应和光化学反应。每章后附有习题精选及解答习题的推荐参考文献。作者：(美国)卡雷 (Carey.F.A.) (美国)松德贝里 (Sundberg.R.J.) Preface
AcknowledgmentandPersonalStatement
Introduction
Chapter1ChemicalBondingandMolecularStructure
Introduction
1.1DescriptionofMolecularStructureUsingValenceBondConcepts
1.1.1Hybridization
1.1.2TheOriginofElectron-ElectronRepulsion
1.1.3ElectronegativityandPolarity
1.1.4ElectronegativityEqualization
1.1.5DifferentialElectronegativityofCarbonAtoms
1.1.6Polarizability，Hardness，andSoftness
1.1.7ResonanceandConjugation
1.1.8Hyperconjugation
1.1.9CovalentandvanderWaalsRadiiofAtoms
1.2MolecularOrbitalTheoryandMethods
1.2.1TheHiickelMOMethod
1.2.2SemiempiricalMOMethods
1.2.3AbInitioMethods
1.2.4PictorialRepresentationofMOsforMolecules
1.2.5QualitativeApplicationofMOTheorytoReactivity：PerturbationalMOTheoryandFrontierOrbitals
1.2.6NumericalApplicationofMOTheory
1.3ElectronDensityFunctionals
1.4RepresentationofElectronDensityDistribution
1.4.1MullikenPopulationAnalysis
1.4.2NaturalBondOrbitalsandNaturalPopulationAnalysis
1.4.3AtomsinMolecules
1.4.4ComparisonandInterpretationofAtomicChargeCalculations
1.4.5ElectrostaticPotentialSurfaces
1.4.6RelationshipsbetweenElectronDensityandBondOrder
Topic1.1TheOriginoftheRotational(Torsional)BarrierinEthaneandOtherSmallMolecules
Topic1.2HeteroatomHyperconjugation(AnomericEffect)inAcyclicMolecules
Topic1.3BondinginCyclopropaneandOtherSmallRingCompounds
Topic1.4RepresentationofElectronDensitybytheLaplacianFunction
Topic1.5ApplicationofDensityFunctionalTheorytoChemicalPropertiesandReactivity
T1.5.1DFTFormulationofChemicalPotential，Electronegativity，HardnessandSoftness，andCovalentandvanderWaalRadii
T1.5.2DFTFormulationofReactivity——TheFukuiFunction..
T1.5.3DFTConceptsofSubstituentGroupsEffects
GeneralReferences
Problems

Chapter2Stereoehemistry，Conformation，andStereoselectivity.."
Introduction
2.1Configuration
2.1.1ConfigurationatDoubleBonds
2.1.2ConfigurationofCyclicCompounds
2.1.3ConfigurationatTetrahedralAtoms
2.1.4MoleculeswithMultipleStereogenicCenters
2.1.5OtherTypesofStereogenicCenters
2.1.6TheRelationshipbetweenChiralityandSymmetry
2.1.7ConfigurationatProchiralCenters
2.1.8Resolution——TheSeparationofEnantiomers
2.2Conformation
2.2.1ConformationofAcyclicCompounds
2.2.2ConformationsofCyclohexaneDerivatives
2.2.3ConformationsofCarbocyclicRingsofOtherSizes
2.3MolecularMechanics
2.4StereoselectiveandStereospecificReactions
2.4.1ExamplesofStereoselectiveReactions
2.4.2ExamplesofStereospecificReactions
2.5EnantioselectiveReactions
2.5.1EnantioselectiveHydrogenation
2.5.2EnantioselectiveReductionofKetones
2.5.3EnantioselectiveEpoxidationofAllylicAlcohols
2.5.4EnantioselectiveDihydroxylationofAlkenes
2.6DoubleStereodifferentiation：ReinforcingandCompetingStereoselectivity
Chapter3StrucralEffectsonStabilityandReactivity
Chapter4NucleophilicSubstitution
Chapter5PolarAdditionandEliminationReactions
Chapter6CarbanionsandOtherCarbonNucleophiles
Chapter7Addition，CondensationandSubstitutionReactionsofCarbonylCompounds
Chapter8Aromatictity
Chapter9AromaticSubstitution
Chapter10ConcertedPericyclicReactions
Chapter11FreeRadicalReactions
Chapter12Photochemistry
ReferencestoProblems
Index
内容简介:
　　《高等有机化学：结构与机理(第5版)》自从1997年面世以来，《高等有机化学》作为学科首选教材的地位一直没有动摇过，广泛地覆盖了有机化合物的结构、反应活性及合成。她的第五版相对2001年出版的第四版进行了大幅度的修订，更新了学科发展的相关资料，内容组织更加清晰明朗，特别是计算化学部分。PartA从化合物结构和立体化学基础概念讲起，涉及有机化学反应热力学和动力学的方方面面。主要反应类型涵盖亲核取代反应、加成反应、碳负离子和羰基化学反应、芳环取代反应、周环反应、自由基反应和光化学反应。每章后附有习题精选及解答习题的推荐参考文献。
作者简介:
作者：(美国)卡雷 (Carey.F.A.) (美国)松德贝里 (Sundberg.R.J.)
目录:
Preface
AcknowledgmentandPersonalStatement
Introduction
Chapter1ChemicalBondingandMolecularStructure
Introduction
1.1DescriptionofMolecularStructureUsingValenceBondConcepts
1.1.1Hybridization
1.1.2TheOriginofElectron-ElectronRepulsion
1.1.3ElectronegativityandPolarity
1.1.4ElectronegativityEqualization
1.1.5DifferentialElectronegativityofCarbonAtoms
1.1.6Polarizability，Hardness，andSoftness
1.1.7ResonanceandConjugation
1.1.8Hyperconjugation
1.1.9CovalentandvanderWaalsRadiiofAtoms
1.2MolecularOrbitalTheoryandMethods
1.2.1TheHiickelMOMethod
1.2.2SemiempiricalMOMethods
1.2.3AbInitioMethods
1.2.4PictorialRepresentationofMOsforMolecules
1.2.5QualitativeApplicationofMOTheorytoReactivity：PerturbationalMOTheoryandFrontierOrbitals
1.2.6NumericalApplicationofMOTheory
1.3ElectronDensityFunctionals
1.4RepresentationofElectronDensityDistribution
1.4.1MullikenPopulationAnalysis
1.4.2NaturalBondOrbitalsandNaturalPopulationAnalysis
1.4.3AtomsinMolecules
1.4.4ComparisonandInterpretationofAtomicChargeCalculations
1.4.5ElectrostaticPotentialSurfaces
1.4.6RelationshipsbetweenElectronDensityandBondOrder
Topic1.1TheOriginoftheRotational(Torsional)BarrierinEthaneandOtherSmallMolecules
Topic1.2HeteroatomHyperconjugation(AnomericEffect)inAcyclicMolecules
Topic1.3BondinginCyclopropaneandOtherSmallRingCompounds
Topic1.4RepresentationofElectronDensitybytheLaplacianFunction
Topic1.5ApplicationofDensityFunctionalTheorytoChemicalPropertiesandReactivity
T1.5.1DFTFormulationofChemicalPotential，Electronegativity，HardnessandSoftness，andCovalentandvanderWaalRadii
T1.5.2DFTFormulationofReactivity——TheFukuiFunction..
T1.5.3DFTConceptsofSubstituentGroupsEffects
GeneralReferences
Problems

Chapter2Stereoehemistry，Conformation，andStereoselectivity.."
Introduction
2.1Configuration
2.1.1ConfigurationatDoubleBonds
2.1.2ConfigurationofCyclicCompounds
2.1.3ConfigurationatTetrahedralAtoms
2.1.4MoleculeswithMultipleStereogenicCenters
2.1.5OtherTypesofStereogenicCenters
2.1.6TheRelationshipbetweenChiralityandSymmetry
2.1.7ConfigurationatProchiralCenters
2.1.8Resolution——TheSeparationofEnantiomers
2.2Conformation
2.2.1ConformationofAcyclicCompounds
2.2.2ConformationsofCyclohexaneDerivatives
2.2.3ConformationsofCarbocyclicRingsofOtherSizes
2.3MolecularMechanics
2.4StereoselectiveandStereospecificReactions
2.4.1ExamplesofStereoselectiveReactions
2.4.2ExamplesofStereospecificReactions
2.5EnantioselectiveReactions
2.5.1EnantioselectiveHydrogenation
2.5.2EnantioselectiveReductionofKetones
2.5.3EnantioselectiveEpoxidationofAllylicAlcohols
2.5.4EnantioselectiveDihydroxylationofAlkenes
2.6DoubleStereodifferentiation：ReinforcingandCompetingStereoselectivity
Chapter3StrucralEffectsonStabilityandReactivity
Chapter4NucleophilicSubstitution
Chapter5PolarAdditionandEliminationReactions
Chapter6CarbanionsandOtherCarbonNucleophiles
Chapter7Addition，CondensationandSubstitutionReactionsofCarbonylCompounds
Chapter8Aromatictity
Chapter9AromaticSubstitution
Chapter10ConcertedPericyclicReactions
Chapter11FreeRadicalReactions
Chapter12Photochemistry
ReferencestoProblems
Index

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高等有机化学-结构与机理(第五版)

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