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高等有机化学：反应与合成

作者: [美] 卡雷著 , [美] 松德贝里著

出版社: 科学出版社

出版时间: 2009-01

版次: 5

ISBN: 9787030238580

定价: 160.00

装帧: 平装

开本: 16开

纸张: 胶版纸

页数: 1321页

字数: 1600千字

正文语种: 英语

原版书名: Advanced Organic Chemistry

分类: 自然科学

4 张插图图片

　　《高等有机化学：反应与合成(第5版)》是《高等有机化学：反应与合成(第5版)》的新版，自从1977年面世以来，《高等有机化学：反应与合成(第5版)》作为学科优选教材的地位一直没有动摇过，广泛地覆盖了有机化合物的结构、反应活性及合成。她的第五版相对2001年出版的第四版进行了大幅度的修订，更新了学科发展的相关资料，内容组织更加清晰明朗，特别是计算化学部分。通过控制反应而得到特定的合成是有机合成的全部目标。PartB在不同反应类型的基础上详尽地描述了最常见的和最有用的合成反应。每章后附有习题精选及解答习题的推荐参考文献。作者：(美国)卡雷 (Carey.F.A.) (美国)松德贝里 (Sundberg.R.J.) Preface
AcknowledgmentandPersonalStatement
Introduction
Chapter1.AlkylationofEnolatesandOtherCarbonNucleophiles
Introduction
1.1.GenerationandPropertiesofEnolatesandOtherStabilizedCarbanions
1.1.1.GenerationofEnolatesbyDeprotonation
1.1.2.RegioselectivityandStereoselectivityinEnolateFormationfromKetonesandEsters
1.1.3.OtherMeansofGeneratingEnolates
1.1.4.SolventEffectsonEnolateStructureandReactivity
1.2.AlkylationofEnolates
1.2.1.AlkylationofHighlyStabilizedEnolates
1.2.2.AlkylationofKetoneEnolates
1.2.3.AlkylationofAldehydes,Esters,CarboxylicAcids,Amides,andNitriles
1.2.4.GenerationandAlkylationofDianions
1.2.5.IntramolecularAlkylationofEnolates
1.2.6.ControlofEnantioselectivityinAlkylationReac:ions
1.3.TheNitrogenAnalogsofEnolsandEnolates:EnaminesandImineAnions
GeneralReferences
Problems
Chapter2.ReactionsofCarbonNucleophileswithCarbonylCompounds
Introduction
2.1.AldolAdditionandCondensationReactions
2.1.1.TheGeneralMechanism
2.1.2.ControlofRegio-andStereoselectivityofAldolReactionsofAldehydesandKetones
　2.1.3.AldolAdditionReactionsofEnolatesofEstersandOtherCarbonylDerivatives
2.1.4.TheMukaiyamaAldolReaction
2.1.5.ControlofFacialSelectivityinAldolandMukaiyamaAldolReactions
2.1.6.IntramolecularAldolReactionsandtheRobinsonAnnulation
2.2.AdditionReactionsofIminesandIminiumIons
2.2.1.TheMannichReaction
2.2.2.AdditionstoN-AcylIminiumIons
2.2.3.Amine-CatalyzedCondensationReactions
2.3.AcylationofCarbonNucleophiles
2.3.1.ClaisenandDieckmannCondensationReactions
2.3.2.AcylationofEnolatesandOtherCarbonNucleophiles
2.4.OlefinationReactionsofStabilizedCarbonNucleophiles
2.4.1.TheWittigandRelatedReactionsofPhosphorus-StabilizedCarbonNucleophiles
　2.4.2.Reactionsofa-TrimethyisilylcarbanionswithCarbonylCompounds
2.4.3.TheJuliaOlefinationReaction
2.5.ReactionsProceedingbyAddition-Cyclization
2.5.1.SulfurYiidesandRelatedNucleophiles
2.5.2.NucleophilicAddition-Cyclizationofot-Haloesters
2.6.ConjugateAdditionbyCarbonNucleophiles
2.6.1.ConjugateAdditionofEnolates
2.6.2.ConjugateAdditionwithTandemAlkylation
2.6.3.ConjugateAdditionbyEnolateEquivalents
2.6.4.ControlofFacialSelectivityinConjugateAdditionReactions
2.6.5.ConjugateAdditionofOrganometallicReagents
2.6.6.ConjugateAdditionofCyanideIon
GeneralReferences
Problems
Chapter3.FunctionalGroupInterconversionbySubstitution,IncludingProtectionandDeprotection
Introduction
3.1.ConversionofAlcoholstoAlkylatingAgents
3.1.1.SulfonateEsters
3.1.2.Halides
……
Chapter4.ElectrophilicAdditionstoCarbon-CarbonMultipleBonds
Chapter5.ReductionofCarbon-CarbonMultipleBonds,CarbonylCroups,andOtherFunctionalGroups
Chapter6.ConcertedCycloadditions,UnimolecularRearrangements,andThermalEliminations
Chapter7.OrganometallicCompoundsofGroupIandIIMetals
Chapter8.ReactionsInvolvingTransitionMetals
Chapter9.Carbon-CarbonBond-FormingReactionsofCompoundsofBoron,Silcon,andTin
Chapter10.ReactionsInvolvingCarbocations,Carbenes,andRadicalsandReactiveIntermediates
Chapter11.AromaticSubstitutionReactions
Chapter12.Oxidations
Chapter13.MultistepSyntheses
References
Index
内容简介:
　　《高等有机化学：反应与合成(第5版)》是《高等有机化学：反应与合成(第5版)》的新版，自从1977年面世以来，《高等有机化学：反应与合成(第5版)》作为学科优选教材的地位一直没有动摇过，广泛地覆盖了有机化合物的结构、反应活性及合成。她的第五版相对2001年出版的第四版进行了大幅度的修订，更新了学科发展的相关资料，内容组织更加清晰明朗，特别是计算化学部分。通过控制反应而得到特定的合成是有机合成的全部目标。PartB在不同反应类型的基础上详尽地描述了最常见的和最有用的合成反应。每章后附有习题精选及解答习题的推荐参考文献。
作者简介:
作者：(美国)卡雷 (Carey.F.A.) (美国)松德贝里 (Sundberg.R.J.)
目录:
Preface
AcknowledgmentandPersonalStatement
Introduction
Chapter1.AlkylationofEnolatesandOtherCarbonNucleophiles
Introduction
1.1.GenerationandPropertiesofEnolatesandOtherStabilizedCarbanions
1.1.1.GenerationofEnolatesbyDeprotonation
1.1.2.RegioselectivityandStereoselectivityinEnolateFormationfromKetonesandEsters
1.1.3.OtherMeansofGeneratingEnolates
1.1.4.SolventEffectsonEnolateStructureandReactivity
1.2.AlkylationofEnolates
1.2.1.AlkylationofHighlyStabilizedEnolates
1.2.2.AlkylationofKetoneEnolates
1.2.3.AlkylationofAldehydes,Esters,CarboxylicAcids,Amides,andNitriles
1.2.4.GenerationandAlkylationofDianions
1.2.5.IntramolecularAlkylationofEnolates
1.2.6.ControlofEnantioselectivityinAlkylationReac:ions
1.3.TheNitrogenAnalogsofEnolsandEnolates:EnaminesandImineAnions
GeneralReferences
Problems
Chapter2.ReactionsofCarbonNucleophileswithCarbonylCompounds
Introduction
2.1.AldolAdditionandCondensationReactions
2.1.1.TheGeneralMechanism
2.1.2.ControlofRegio-andStereoselectivityofAldolReactionsofAldehydesandKetones
　2.1.3.AldolAdditionReactionsofEnolatesofEstersandOtherCarbonylDerivatives
2.1.4.TheMukaiyamaAldolReaction
2.1.5.ControlofFacialSelectivityinAldolandMukaiyamaAldolReactions
2.1.6.IntramolecularAldolReactionsandtheRobinsonAnnulation
2.2.AdditionReactionsofIminesandIminiumIons
2.2.1.TheMannichReaction
2.2.2.AdditionstoN-AcylIminiumIons
2.2.3.Amine-CatalyzedCondensationReactions
2.3.AcylationofCarbonNucleophiles
2.3.1.ClaisenandDieckmannCondensationReactions
2.3.2.AcylationofEnolatesandOtherCarbonNucleophiles
2.4.OlefinationReactionsofStabilizedCarbonNucleophiles
2.4.1.TheWittigandRelatedReactionsofPhosphorus-StabilizedCarbonNucleophiles
　2.4.2.Reactionsofa-TrimethyisilylcarbanionswithCarbonylCompounds
2.4.3.TheJuliaOlefinationReaction
2.5.ReactionsProceedingbyAddition-Cyclization
2.5.1.SulfurYiidesandRelatedNucleophiles
2.5.2.NucleophilicAddition-Cyclizationofot-Haloesters
2.6.ConjugateAdditionbyCarbonNucleophiles
2.6.1.ConjugateAdditionofEnolates
2.6.2.ConjugateAdditionwithTandemAlkylation
2.6.3.ConjugateAdditionbyEnolateEquivalents
2.6.4.ControlofFacialSelectivityinConjugateAdditionReactions
2.6.5.ConjugateAdditionofOrganometallicReagents
2.6.6.ConjugateAdditionofCyanideIon
GeneralReferences
Problems
Chapter3.FunctionalGroupInterconversionbySubstitution,IncludingProtectionandDeprotection
Introduction
3.1.ConversionofAlcoholstoAlkylatingAgents
3.1.1.SulfonateEsters
3.1.2.Halides
……
Chapter4.ElectrophilicAdditionstoCarbon-CarbonMultipleBonds
Chapter5.ReductionofCarbon-CarbonMultipleBonds,CarbonylCroups,andOtherFunctionalGroups
Chapter6.ConcertedCycloadditions,UnimolecularRearrangements,andThermalEliminations
Chapter7.OrganometallicCompoundsofGroupIandIIMetals
Chapter8.ReactionsInvolvingTransitionMetals
Chapter9.Carbon-CarbonBond-FormingReactionsofCompoundsofBoron,Silcon,andTin
Chapter10.ReactionsInvolvingCarbocations,Carbenes,andRadicalsandReactiveIntermediates
Chapter11.AromaticSubstitutionReactions
Chapter12.Oxidations
Chapter13.MultistepSyntheses
References
Index

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高等有机化学：反应与合成

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目录: